I posted many texts about Small Business Role Center in Microsoft Dynamics NAV 2013R2. If you need all on one place, you can use this toc:

Basic Information:

1: https://community.dynamics.com/nav/b/nav4construction/archive/2013/10/10/nav2013r2-small-business-role-center-1.aspx

2: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/02/nav2013r2-small-business-role-center-2.aspx

3: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/02/nav2013r2-small-business-role-center-3.aspx

4: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/03/nav2013r2-small-business-role-center-4.aspx

5: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/04/nav2013r2-small-business-role-center-5.aspx

Setup:

Company Information: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/04/nav2013r2-small-business-role-center-company-information.aspx

General Ledger Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/05/nav2013r2-small-business-role-center-general-ledger-setup.aspx

Sales & Receivables Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/06/nav2013r2-small-business-role-center-sales-amp-receivables-setup.aspx

Purchase & Payables Seup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/08/nav2013r2-small-business-role-center-purchase-amp-payables-setup.aspx

Inventory Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/09/nav2013r2-small-business-role-center-inventory-setup.aspx

Fixed Assets Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/09/nav2013r2-small-business-role-center-fixed-assets-setup.aspx

Human Resources Setup: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/10/nav2013r2-small-business-role-center-human-resource-setup.aspx

Conclusion: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/10/nav2013r2-small-business-role-center-setup-conclusion.aspx

Other:

Bookkeeping: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/11/nav2013r2-small-business-role-center-bookkeeping.aspx

Analysis: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/12/nav2013r2-small-business-role-center-analysis.aspx

Bank & Payments / VAT Reporting: https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/16/nav2013r2-small-business-role-center-bank-and-vat.aspx

When?

https://community.dynamics.com/nav/b/nav4construction/archive/2013/11/19/nav2013r2-sb-role-center-and-when-my-basic-account-system-outgrown.aspx