It's a lot to describe for each of those columns/lines :)
In the Standard Cost column, You would get Item costs, only if the Finished good item has the Costing Method of Standard, and in the Item card, You have the Standard cost provided. In the picture above it is the worksheet, that I think You have to approve, before the Standard Cost field is updated in the Item Card. and after that You have to re-plan the Prod Order, so that the Costs are updated (or delete and create the Line in production order again)
For other lines I think this column is always 0.
For the Capacity and Labor Cost, You would need to post Capacity Ledger entries with information how much time has a work center or machine center was used for this Prod. order. In the same way if You provide information of how much time Resource (person) has spent time on each operation, then You will get the Labor Costs,
The Expected cost is when the Prod. Order is planned and You have all the costs in Work center cards and resource cards.
The Actual costs appear when those entries are posted with how much time actually has been spent. Then You can see the Deviation percentage.