Hi Jainam and Oussamma, thank you so much for helping me out.
Here's a view of my data, it's mostly default.
In my BC, I have added the Units of Measure (For the PRIMUNIT, I tried renaming the Primary Unit in D365 sales so it'll match to the BC record, but still didn't work; I tried filtering the records to be synced to only Sync the PRIMUNIT, thinking that the relationship with the EA record and PRIMUNIT might be and issue too, didn't work)
Integration Table Mappings:
Coupling criteria:
Error I'm getting,