You are trying to add a column at Purchase order header level, but purchase requisition has relation with Purchase order lines because single PO can be created against multiple Purchase requisitions.
So, if you need Purchase order and purchase requisition in a excel, you should export the purchase order lines data. In the below screenshot, it is showing open purchase order lines, you just need to remove the filter from Advanced Filter option or by adding a column of Status, along with column of purchase requisition. then you can export the data.
Regards,
Neeraj Kumar
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