How do I complain about PhonePe payments. To raise a complaint on PhonePe, you can contact their customer service team either through phone at (8001001410 )at call email, 8OOI-OOI-4IO or through their website's customer support portal..How do I complain about PhonePe payments? To raise a complaint on PhonePe, you can contact their customer service team either through phone at (800100+1410 )at call email, 8001001410..or through their website's customer support portal.. help@phonepe.com How do I raise a complaint.