Alternate Key Design Between F&O and Customer Service
What do you mean exactly by not being able to edit keys on the Dataverse side?
It is correct, you cannot edit keys in a managed solution, but you are able to define your own keys.
Have you installed any of the orchestration packages? It should contain the mappings out of the box, and additional fields needed in Dataverse, such as a reference to the company table for entities that are per legal entity such as customers and vendors.