Unfortunately NAV does not have timestamps on records. Have to upgrade to BC for that or else create your timestamps yourself with custom fields. We've been using NAV for 12 years and so we have LOTS of "Created At" and "Created By" custom fields throughout the system--with custom code to populate them.
The key question here is when you say "lines added later", how do you define "later". Some users will create PO lines quickly, others more slowly. Sometimes a user might get interrupted and come back hours later (if not the next day) to finish creating the PO lines.
Once you have that defined, then a custom field (or maybe 2) and a little custom code "OnInsertPurchaseLine" should be fairly easy to write for any NAV Developer.