I think I understand the logic behind this now...
The route I see looks like this:
10 Op1 (real name FCUT) Next = 30 from Route1
20 Op3 (real name SOFTSEAT1) Next = 0 from Route 2
30 Op2 (Real name SEW) Next = 0 from Route 1
When I go to Gantt chart I see FCUT and SOFTSEAT1 start at the same time (why wouldn't they as they were both at sequence 10 in their respective routes and the phantoms are at the same level in the BOM?)
As Next = 30 on FCUT, SEW cant start until FCUT is complete so it appears third in the list of operations

I think that makes sense once you realise that FCUT and SOFTSEAT1 are created in parallel