D365BC Team Member licenses users cant create PO, but they can create PQ's and send those for approval. You also also use Power Automate or AL dev to do the 'make order' action on apprroved PQ's (as an automation for the essential licensed user that would otehrwise have to maually click 'make order' on these).
If you're referring to the Business Central Team Member License, it allows a user to create quotes but not orders, meaning you won't be able to create a purchase order. However, it does permit users to send documents for approval, so you will be able to send existing orders for approval.
If I remember correctly, a team license user could create a quote but not able to create a purchase or sales order. Such users are able to use workflow, such as send for approval or approve a workflow request.
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