Hi Ganesh.
Hope you are doing well.
Request you to please check the below link and see if that answer your concern.
support.microsoft.com/.../frequently-asked-questions-about-the-mail-merge-feature-in-word-2003-w
Q15: Can I add an attachment when performing a merge to an e-mail message?
A15: No, you cannot add an attachment when performing a merge to an e-mail message. Microsoft Office Word doesn’t support this functionality. However, you can add an attachment when performing a merge to an e-mail message programmatically by using CDOSys. You can contact a solution provider to build solution for you.
Q16: How I can add attachments when doing a merge to e-mail?
A16: Microsoft Word doesn’t support this functionality. However, this can be done programmatically by using CDOSys. You can contact a solution provider to build a solution for you.
For more information, click the following article number to view the article in the Microsoft Knowledge Base:
310212 How to use the Cdosys.dll library to send an e-mail message with attachments by using Visual C#
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