Hi praveens007,
You can do the following:
1. AR/setup/forms/formsetup/print management button

Here you can specify a condition that looks for example for the existance of a specific email. If the email is missing then the default print setting is used. That is, the document can then e.g. be printed on a printer
2. Then open the customer account statement and make sure that the print management setting is selected.
Note that I did not make a selection in the from and to date fields. If you want you can select the 'open only' button to list only open transactions in the statement.

The destination defaults from the print settings and you have to define the recurrence (e.g. monthly)

Also ensure that you enable the batch processing parameter and select a batch group.
That's basically the process.
If you need more examples, have a look at my blog where I posted similar things for sending payment advices and other things.
The key to all of that is that you have good and complete customer master data that have all an email assigned.
Best regards,
Ludwig